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Synthesis and properties of novel organogelators functionalized with 5-iodo-1,2,3-triazole and azobenzene

Ziyan Li,Yaodong Huang,Dongli Fan,Huimin Li,Shuxue Liu,Luyuan Wang

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 4, Pages 552-561 doi: 10.1007/s11705-016-1589-8

Abstract: Two series of 5-iodo-1,2,3-triazole derivatives containing azobenzene group(s) were synthesized and their

Keywords： iodo triazole azobenzene photoresponsive organogel gelator-solvent effect

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Novel 1,2,3-triazole-based compounds: Iodo effect on their gelation behavior and cation response

Yaodong Huang, Shuxue Liu, Zhuofeng Xie, Zipei Sun, Wei Chai, Wei Jiang

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 2, Pages 252-261 doi: 10.1007/s11705-017-1683-6

Abstract: Two new series of 1,2,3-triazole derivatives, with and without iodo substitution, were synthesized andIt was found that the iodo substitution at position 5 of triazole ring could greatly enhance the gelationScanning electron microscopy and X-ray diffraction reveal that the structures of the organogels from iodoIodo gels are selectively responsive to the stimuli of Hg , whereas hydrogenous gels can respond to Hgexistence of halogen bonding interaction in the iodo compounds.

Keywords： organogelator 1 2 3-triazole derivatives self-assembly halogen bonding cation response